A novel, shape-selective, zeolite-catalyzed synthesis of calix(4) pyrroles

Radha Kishan, M. ; Srinivas, N. ; Raghavan, K. V. ; Kulkarni, S. J. ; Sarma, J. A. R. P. ; Vairamani, M. (2001) A novel, shape-selective, zeolite-catalyzed synthesis of calix(4) pyrroles Chemical Communication (21). pp. 2226-2227. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2001...

Related URL: http://dx.doi.org/10.1039/B105690P

Abstract

Porosity and acidity of molecular sieve Al-MCM-41 (ca. 30 Å pore diameter) plays a crucial role in the synthesis of novel calix(4)pyrroles; for the first time, Al-MCM-41 has been used as a solid acid catalyst to produce a number of calix(4)pyrroles with good selectivity and yields where zeolite HY (ca. 7.6 Å pore diameter) yields mainly the linear chain dimer and no cyclic products.

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