Joshi, A. P. ; Nayak, U. R. ; Sukh Dev, (1976) Studies in sesquiterpenes-L: 3-hydroxylongifolaldehyde, the elusive intermediate in the abnormal perbenzoic acid oxidation of longifolene Tetrahedron, 32 (12). pp. 1423-1425. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4020(76)85023-5
Abstract
The isolation and stereochemistry of 3-hydroxylongifolaldehyde (4), the missing key-compound in the earlier proposed mechanism for the abnormal perbenzoic acid oxidation of longifolene is described. Rearrangement of hydroxyaldehyde (4) to hydroxyketone (6) during exposure to LAH is reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 54480 |
| Deposited On: | 11 Aug 2011 14:32 |
| Last Modified: | 11 Aug 2011 14:32 |
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