Studies in sesquiterpenes-XLIV 1: Isolongifolene (Part 5): Rearrangement of isolongifolene epoxide

Santhanakrishnan, T. S. ; Sobti, R. R. ; Nayak, U. R. ; Sukh Dev, (1970) Studies in sesquiterpenes-XLIV 1: Isolongifolene (Part 5): Rearrangement of isolongifolene epoxide Tetrahedron, 26 (2). pp. 657-662. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)97859-7

Abstract

Isolongifolene epoxide undergoes novel rearrangements on treatment with 1% HCl in CHCl3 or on being exposed to active adsorbent (Al2O3, SiO2-gel). The latter reaction leads to tetracarbocylic derivatives. These reactions fully substantiate the stereochemistry assigned earlier to isolongifolene epoxide.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:53981
Deposited On:10 Aug 2011 09:01
Last Modified:10 Aug 2011 09:01

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