Chemistry of ayurvedic crude drugs-IV: Guggulu (resin from commiphora mukul-4 absolute stereochemistry of mukulol

Prasad, R. S. ; Sukh Dev, (1976) Chemistry of ayurvedic crude drugs-IV: Guggulu (resin from commiphora mukul-4 absolute stereochemistry of mukulol Tetrahedron, 32 (12). pp. 1437-1441. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0040-4020(76)85026-0

Abstract

Absolute stereochemistry of mukulol, a diterpene alcohol, is established by chemical correlation with cembrene-A and (+)-cis-piperitol. Synthesis of (+)-cis-piperitol and (-)-trans-piperitol from (+)-Δ2-carene is described. Δ2-Carene oxide on exposure to silica gel passes into cis Δ2-p-menthen-1,8-diol.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:53952
Deposited On:10 Aug 2011 09:12
Last Modified:10 Aug 2011 09:12

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