Shastri, Mayank H. ; Sukh Dev, (1992) Studies in sesquiterpenes-lx reversion of longipinane to himachalane system: revision of structure of isocentdarol Tetrahedron, 48 (23). pp. 4905-4918. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)81583-0
Abstract
Longipinene on exposure to acids rapidly rearranges to furnish α- and β-himachalenes, longifolene and isolongifolene. Longipinene epoxide, under acid catalysis, gives several products resulting from fragmentation and Wagner-Meerwein rearrangement. All products have been fully characterised. Formation of isocentdarol in this reaction requires revision of its stereochemistry at the centre carrying tertiary hydroxyl function.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 53935 |
| Deposited On: | 10 Aug 2011 09:11 |
| Last Modified: | 10 Aug 2011 11:37 |
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