Evidence for the involvement of silver nanoclusters during the Wolff rearrangement of α-diazoketones

Sudrik, Surendra G. ; Maddanimath, Trupti ; Chaki, Nirmalya K. ; Chavan, Sambhaji P. ; Chavan, Subhash P. ; Sonawane, Harikisan R. ; Vijayamohanan, K. (2003) Evidence for the involvement of silver nanoclusters during the Wolff rearrangement of α-diazoketones Organic Letters, 5 (13). pp. 2355-2358. ISSN 1523-7060

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/ol034747g

Related URL: http://dx.doi.org/10.1021/ol034747g

Abstract

In situ-generated silver nanoclusters(Agn) during the reduction of either silver(I) oxide or other salts presumably catalyze the Wolff rearrangement of α -diazoketones. Their optical, physical, and catalytic properties depend on the starting silver(I) compound and the reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:53285
Deposited On:05 Aug 2011 11:16
Last Modified:05 Aug 2011 11:16

Repository Staff Only: item control page