Twisted intramolecular charge transfer emission of dimethylaminobenzonitrile in α -cyclodextrine cavities

Nag, Ashis ; Bhattacharyya, Kankan (1988) Twisted intramolecular charge transfer emission of dimethylaminobenzonitrile in α -cyclodextrine cavities Chemical Physics Letters, 151 (4-5). pp. 474-476. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(88)85172-8

Abstract

The absorption and emission of 4-(N,N-dimethylamino)benzonitrile (DMABN) in a-cyclodextrine (α -CD) cavities is reported. The twisted intramolecular charge transfer emission is enhanced on complexation with α -CD. This is attributed to the reduced polarity of the CD environment.

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