Core-modified octaphyrins: syntheses and anion-binding properties

Misra, Rajneesh ; Anand, Venkataramana Rao G. ; Rath, Harapriya ; Chandrashekar, Tavarekere K. (2005) Core-modified octaphyrins: syntheses and anion-binding properties Journal of Chemical Sciences, 117 (2). pp. 99-103. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/chemsci/Pdf-Mar2005/99.pdf

Abstract

In this paper, a brief review of the syntheses, characterization and anion-binding properties of core-modified octaphyrins is presented. It has been shown that the core-modified octaphyrins exhibit aromaticity both in solution and in solid state, confirming the validity of the (4n + 2) Huckel rule for larger π-electron systems. Solid-state binding characteristics of TFA anions of two core-modified octaphyrins are also described.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Anion Binding; Aromaticity; 34π Electrons; Octaphyrin; Oxidative Coupling Reactions
ID Code:5271
Deposited On:18 Oct 2010 07:47
Last Modified:16 May 2016 15:48

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