Synthesis and properties of o-containing Chevrel phases, AxMo6S6O2 (A=Co, Ni, Cu and Pb)

Umarji, A. M. ; Subba Rao, G. V. ; Sankaranarayana, V. ; Rangarajan, G. ; Srinivasan, R. (1980) Synthesis and properties of o-containing Chevrel phases, AxMo6S6O2 (A=Co, Ni, Cu and Pb) Materials Research Bulletin, 15 (7). pp. 1025-1031. ISSN 0025-5408

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0025-5408(80)90229-9

Abstract

Oxygen containing Chevrel phases, AxMo6S6O2 (Ax=Co2,Ni2,Cu2,Pb) and Mo6S6O2 have been synthesized and electrical and superconducting properties examined. These exhibit physical properties quite akin to the corresponding -S8 phases. However, differences in ionic size and electronegativity between O and S bring about subtle changes in Tc and Tt after O-incorporation.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:52051
Deposited On:01 Aug 2011 14:25
Last Modified:01 Aug 2011 14:25

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