Sharma, N. ; Shaju, K. M. ; Subba Rao, G. V. ; Chowdari, B. V. R. (2002) Sol-gel derived nano-crystalline CaSnO3 as high capacity anode material for Li-ion batteries Electrochemistry Communications, 4 (12). pp. 947-952. ISSN 1388-2481
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S1388-2481(02)00495-2
Abstract
CaSnO3 with the distorted-perovskite structure was prepared by sol-gel and high temperature solid-state reaction and electrochemical properties were studied in cell with Li as counter electrode. The sol-gel method gave uniform nano-crystallites (200-300 nm) of CaSnO3 and was shown to deliver a reversible capacity of 380 mAh/g (0.005-1.0 V; 60 mA/g) with good cycling stability up to 45 cycles. The observed capacity involved in the first-discharge and the reversible capacity values during subsequent charge-discharge cycles show that the electrochemical process in CaSnO3 is similar to other Sn-containing mixed oxide systems, viz., an initial structural reduction with Sn-metal formation followed by reversible Li-Sn alloy formation. The performance with respect to the attainable capacity, its retention on charge-discharge cycling and rate capability is better than the previously reported best-performing bulk Sn-oxide or ATCO starting materials which reveals that the perovskite structure and Ca-ion play a beneficial role.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Anode Material; CaSnO3; Li-ion Battery; Nano-crystallites |
ID Code: | 52033 |
Deposited On: | 02 Aug 2011 08:21 |
Last Modified: | 02 Aug 2011 08:21 |
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