Bera, Tushar Kanti ; Sivaram, Swaminathan (1995) 2-Perbromomethyl-2-oxazoline: a novel trifunctional initiator for the ring-opening polymerization of 2-methyl-2-oxazoline Macromolecular Chemistry and Physics, 196 (5). pp. 1515-1522. ISSN 1022-1352
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/macp.19...
Related URL: http://dx.doi.org/10.1002/macp.1995.021960513
Abstract
Polymerization of 2-methyl-2-oxazoline was carried out using a trifunctional initiator, 2-perbromomethyl-2-oxazoline. The degree of polymerization (DP) of the resulting polymer was very close to the feed mole ratio of the monomer to initiator. The number-average molecular weight M-n increased linearly with conversion, indicating the living nature of the propagating chain end. 1H NMR and end-group analyses results are consistent with the proposal that the polymer possesses a star-shaped structure.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 51645 |
| Deposited On: | 29 Jul 2011 03:59 |
| Last Modified: | 29 Jul 2011 03:59 |
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