Long and short brick network architecture: role of water molecules acting as three-connecting spacers

Banthia, Sandip ; Samanta, Anunay (2006) Long and short brick network architecture: role of water molecules acting as three-connecting spacers Crystal Growth & Design, 6 (2). pp. 360-362. ISSN 1528-7483

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Official URL: http://pubs.acs.org/doi/abs/10.1021/cg050517s

Related URL: http://dx.doi.org/10.1021/cg050517s

Abstract

Crystallization of N-butyl-4-(3-(dimethylamino)-propylamino)-1,8-naphthalimide (1) from moist hexane affords the 1:1 hydrate, 1·H2O, which exhibits a strong intermolecular hydrogen bonding network leading to a not so commonly encountered "long and short brick" architecture influenced by interspersed water molecules. In contrast, an analogous system, N-butyl-4-(2-(dimethylamino)-ethylamino)-1,8-naphthalimide (2), which crystallizes without the water molecule, does not display a long and short brick tiling pattern.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:51615
Deposited On:29 Jul 2011 04:05
Last Modified:29 Jul 2011 04:05

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