Formal total synthesis of (±)-herbertene-1,13-diol and (±)-α-herbertenol via ireland ester claisen rearrangement and RCM reaction sequence

Srikrishna, A. ; Vasantha Lakshmi, B. (2005) Formal total synthesis of (±)-herbertene-1,13-diol and (±)-α-herbertenol via ireland ester claisen rearrangement and RCM reaction sequence Synlett, 2005 (7). pp. 1173-1175. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2005-865223

Abstract

A combination of Ireland ester Claisen rearrangement and ring-closing metathesis (RCM) reactions has been employed for efficient formal total syntheses of herbertene-1,13-diol and α-herbertenol, sesquiterpenes containing two vicinal quaternary carbon atoms on a cyclopentane ring.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:(±)-Herbertene-1,13-diol; (±)-α-Herbertenol; Ireland Ester Claisen Rearrangement
ID Code:51573
Deposited On:28 Jul 2011 14:33
Last Modified:28 Jul 2011 14:33

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