Chiral synthons from monoterpenes. Stereoselective syntheses of (−)5S, 6S, 9R-6-isopropyl-9-methyl-2-oxaspiro [4.4] nonan-3-one and (−) 3aR, 6R, 7aR-3a- methyl-6-isopropenylhexahydrobenzofuran-2-one

Srikrishna, A. ; Sharma, G. V. R. ; Nagaraju, S. (1992) Chiral synthons from monoterpenes. Stereoselective syntheses of (−)5S, 6S, 9R-6-isopropyl-9-methyl-2-oxaspiro [4.4] nonan-3-one and (−) 3aR, 6R, 7aR-3a- methyl-6-isopropenylhexahydrobenzofuran-2-one Synthetic Communications, 22 (9). pp. 1221-1230. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397919208019303

Abstract

Highly stereoselective syntheses of two C-12 chiral synthons 3 and 9, mentioned in the title, starting from the monoterpenes R-1 imonene and R-carvone, using radical cyc 1 sation as key reaction, are described.

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