Srinivasan, Alagar ; Pushpan, Simi K. ; Ravikumar, Murugaeson ; Chandrashekar, Tavarekere K. ; Roy, Raja (1999) Novel heteroatom containing rubyrins Tetrahedron, 55 (21). pp. 6671-6680. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4020(99)00313-0
Abstract
Synthesis of rubyrins containing two or three heteroatoms (O, S, Se) in the core is accomplished using modified diols and tetrapyrromethanes. Substitution of heteroatoms leads to significant reductions in HOMO-LUMO gap and easier oxidations and reductions reflecting the changes in electronic structure of the rubyrin skeleton.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 5149 |
| Deposited On: | 18 Oct 2010 06:17 |
| Last Modified: | 27 May 2011 11:41 |
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