Model for infrared and Raman studies of molecular rotations in liquids and gases

Abstract

Experimental infrared and Raman data for molecular rotations in dense phases often lie in between the results predicted by the J- and M-diffusion models of Gordon. In this paper, we present a theory which is similar in its basic approach to Gordon's extended diffusion models (EDM) but in which the restrictions of the J and M limits are removed. The outcome is a scheme which allows one to describe situations which fall between the two extreme pictures of the J and M models. Application of this scheme to experiments is discussed.