Synthesis and photodimerization in self-assembled monolayers of 7-(8-trimethoxysilyloctyloxy)coumarin

Fang, Jiyu ; Whitaker, Craig ; Weslowski, Brian ; Chen, Mu-Sen ; Naciri, Jawad ; Shashidhar, Ranganathan (2001) Synthesis and photodimerization in self-assembled monolayers of 7-(8-trimethoxysilyloctyloxy)coumarin Journal of Materials Chemistry, 11 . pp. 2992-2995. ISSN 0959-9428

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2001...

Related URL: http://dx.doi.org/10.1039/B102980K

Abstract

We report a synthesis of 7-(8-trimethoxysilyloctyloxy)coumarin that can self-assemble into optically active monolayers on substrates. Atomic force microscopy and UV-vis spectroscopy have been used to characterize the self-assembly processes and photochemical reaction of the coumarin silane on substrates. We also show that when irradiated with linearly polarized UV light, the self-assembled coumarin monolayer can induce a homogeneous alignment of nematic liquid crystals.

Item Type:Article
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ID Code:49499
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