Vibronic contributions to charge transport across molecular junctions

Kushmerick, James G. ; Lazorcik, Jason ; Patterson, Charles H. ; Shashidhar, Ranganathan ; Seferos, Dwight S. ; Bazan, Guillermo C. (2004) Vibronic contributions to charge transport across molecular junctions Nano Letters, 4 (4). pp. 639-642. ISSN 1530-6984

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Official URL: http://pubs.acs.org/doi/abs/10.1021/nl049871n

Related URL: http://dx.doi.org/10.1021/nl049871n

Abstract

We report low-temperature charge transport measurements of metal-molecule-metal junctions. Studies on insulating alkyl and π-conjugated molecular wires provide experimental insight into the coupling between tunnel charge carriers and molecular vibrations in molecular electronic systems. By comparison with other vibrational spectroscopy studies and density functional theory calculations, the observed vibrational peaks have been assigned to longitudinal modes of the molecules.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:49491
Deposited On:20 Jul 2011 09:53
Last Modified:20 Jul 2011 09:53

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