Structural, magnetic and Mössbauer studies on MnxFe3-xO4

Bakare, P P ; Gupta, M P ; Date, S K ; Sinha, A P B (1984) Structural, magnetic and Mössbauer studies on MnxFe3-xO4 Journal of Chemical Sciences, 93 (8). pp. 1349-1359. ISSN 0377-8444

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Official URL: http://www.ias.ac.in/j_archive/chemsci/93/vol93con...

Related URL: http://dx.doi.org/10.1007/BF02869943

Abstract

Polycrystalline samples of Mn x Fe3-x O4 have been prepared following a novel route involving a reaction of desired quantities of stabilized MnO and FeO with Fe2O3 at high temperatures. The novel route of preparation of pure Mnx Fe3-x O4 precludes the presence of Mn3+ and Fe2+ ions. These samples have been characterized for their structural and magnetic properties using x-ray diffraction, Fe57 Mössbauer spectroscopy and bulk magnetic measurements such as initial permeability, loss factor, remanence and coercivity. All our experimental data clearly show the formation of single cubic phase over the entire range of composition. The degree of inversion in these systems decreases with increasing manganese concentration.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Mnx Fe3-x O4; Stabilized MnO and FeO; Mössbauer Studies
ID Code:49008
Deposited On:18 Jul 2011 09:56
Last Modified:20 Jul 2011 10:18

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