Enantiospecific total synthesis of (+)-2-pupukeanone

Srikrishna, Adusumilli ; Jagadeeswar Reddy, Thumkunta (1997) Enantiospecific total synthesis of (+)-2-pupukeanone Journal of the Chemical Society, Perkin Transactions 1 (22). pp. 3293-3294. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1997...

Related URL: http://dx.doi.org/10.1039/A706321K

Abstract

The first total synthesis of chiral 2-pupukeanone (+)-4, starting from R-carvone (−)-7 employing a 5-exo-trig radical cyclisation as the key reaction for the construction of the tricyclic isotwistane carbon framework, is described.

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