Srikrishna, A. ; Nagaraju, Gopalasetty ; Ravi, G. (2010) An enantiospecific approach to the 5-8-5 tricyclic system of basmanes Synlett (20). pp. 3015-3018. ISSN 0936-5214
Full text not available from this repository.
Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0030-1259073
Abstract
An enantiospecific synthesis of the 5-8-5 tricyclic ring system present in the basmane diterpenes has been accomplished, starting from ethyl 3-isopropyl-2-methylene-1-methylcyclopentaneacetate [readily available in five steps from (R)-limonene] employing an RCM reaction for the annulation of cyclooctane and an intramolecular rhodium carbenoid CH insertion reaction for the construction of the cyclopentane ring.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Basmanes; Fusicoccanes; Enantiospecific Synthesis; Metathesis; Rhodium Carbenoid CH Insertion |
| ID Code: | 48823 |
| Deposited On: | 15 Jul 2011 12:32 |
| Last Modified: | 15 Jul 2011 12:32 |
Repository Staff Only: item control page
