Bridged systems via radical cyclisations: synthesis of chiral bicyclo [3.3. 1] nonanes by sequential inter-and intra-molecular radical Michael addition

Srikrishna, Adusumilli ; Hemamalini, Parthasarathy (1989) Bridged systems via radical cyclisations: synthesis of chiral bicyclo [3.3. 1] nonanes by sequential inter-and intra-molecular radical Michael addition Journal of the Chemical Society, Perkin Transactions 1 (12). pp. 2511-2513. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1989...

Related URL: http://dx.doi.org/10.1039/P19890002511

Abstract

A stereoselective synthesis of functionalised chiral bicyclo[3.3.1]nonanes, by a sequential inter- and intra-molecular radical Michael addition of the radical (4), generated in two steps from (S)-carvone (1), in the presence of an excess radicophile (5), is described.

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