Enantiospecific total synthesis of both enantiomers of 2-thiocyanatoneopupukeanane from (R)-carvone

Srikrishna, A. ; Gharpure, Santosh J. (2000) Enantiospecific total synthesis of both enantiomers of 2-thiocyanatoneopupukeanane from (R)-carvone Journal of the Chemical Society, Perkin Transactions 1 (19). pp. 3191-3193. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2000...

Related URL: http://dx.doi.org/10.1039/B005943I

Abstract

Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanane starting from (R)-carvone, employing an intramolecular rhodium carbenoid C-H insertion reaction as the key step, is described.

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