Total synthesis of HM-1 and HM-2, aromatic sesquiterpenes isolated from the phytopathogenic fungus Helicobasidium mompa. Structure revision of HM-2

Srikrishna, A. ; Ravikumar, P. C. (2006) Total synthesis of HM-1 and HM-2, aromatic sesquiterpenes isolated from the phytopathogenic fungus Helicobasidium mompa. Structure revision of HM-2 Tetrahedron Letters, 46 (36). pp. 6105-6109. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.06.156

Abstract

The structure assigned to the sesquiterpene HM-2 was found to be incorrect by total synthesis. A ring-closing metathesis based strategy was developed for the total synthesis of the aromatic sesquiterpene HM-1, which on functional group transformation established the structure of HM-2 as 23, a cuparene derivative.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:HM-1 to 4; Structure Revision; Herbertenoids; Cuparenoids; RCM
ID Code:48791
Deposited On:15 Jul 2011 11:49
Last Modified:15 Jul 2011 11:49

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