Srikrishna, A. ; Satyanarayana, G. (2006) Total synthesis of (±)-herbertenediol Tetrahedron, 62 (12). pp. 2892-2900. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2006.01.021
Abstract
A formal total synthesis of the sesquiterpene (±)-herbertenediol and its dimers mastigophorenes A-D has been accomplished, starting from vanillin via 2,3-dimethoxy-5-methylbenzaldehyde. A combination of Claisen rearrangement and ring-closing metathesis reactions were employed for the generation of the two vicinal quaternary carbons on a cyclopentane ring.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Herbertanes; Mastigophorenes; RCM Reaction; Claisen Rearrangement; Vicinal Quaternary Carbon Atoms |
| ID Code: | 48776 |
| Deposited On: | 15 Jul 2011 11:47 |
| Last Modified: | 15 Jul 2011 11:47 |
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