Srikrishna, A. ; Vasantha Lakshmi, B. (2005) Construction of vicinal quaternary carbon atoms by Ireland ester Claisen rearrangement: total synthesis of (±)-herbertenolide, (±)-herberteneacetal, (±)-herbertene-1,14-diol and (±)-herbertene-1,15-diol Tetrahedron Letters, 46 (29). pp. 4879-4881. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.05.065
Abstract
Efficient total syntheses of the herbertane sesquiterpene title compounds have been accomplished employing an Ireland ester Claisen rearrangement and ring-closing metathesis reaction sequence based strategy for the construction of two stereogenic vicinal quaternary carbon atoms on a cyclopentane.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ireland-Claisen Rearrangement; RCM Reaction; Herbertanes; Vicinal Quaternary Carbon Atoms |
| ID Code: | 48771 |
| Deposited On: | 15 Jul 2011 11:47 |
| Last Modified: | 15 Jul 2011 11:47 |
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