Tributyltin chloride-sodium cyanoborohydride mediated tandem radical cyclisation-reductive demethoxylation sequence

Srikrishna, A. ; Viswajanani, R. ; Yelamaggad, C. V. (1997) Tributyltin chloride-sodium cyanoborohydride mediated tandem radical cyclisation-reductive demethoxylation sequence Tetrahedron, 53 (30). pp. 10479-10488. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(97)00658-3

Abstract

Reaction of the bromoketals 3, 7a-g and 11 with tri-n-butyltin chloride and sodium cyanoborohydride in the presence of a catalytic amount of AIBN furnished the ethers 5, 8a-g and 13 via a tandem sequence comprising of a radical cyclisation reaction and tri-n-butylhalostannane and sodium cyanoborohydride mediated reductive demethoxylation of the resulting cyclic ketals.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:48763
Deposited On:15 Jul 2011 11:33
Last Modified:15 Jul 2011 11:33

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