Srikrishna, A. ; Dethe, Dattatraya H. (2005) An efficient construction of a C3-symmetric macrocycle by head to tail cyclotrimerization of an unsymmetrical diene via a sequence of highly regio- and stereoselective metathesis reactions Tetrahedron Letters, 46 (19). pp. 3381-3383. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.03.088
Abstract
A sequence of highly regio- and stereoselective intermolecular metatheses followed by ring-closing metathesis of an 1-allyl-3-(3-butenyl)cyclohexanol led to a C3-symmetric head to tail cyclic trimer; a 24-membered macrocycle containing three inward directed hydroxyl groups creating a hydrophilic cavity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | RCM Reaction; Cyclotrimerization; AB-ring of Taxanes; Enantiospecific Synthesis |
| ID Code: | 48742 |
| Deposited On: | 15 Jul 2011 11:45 |
| Last Modified: | 15 Jul 2011 11:45 |
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