An enantiospecific synthesis of (−)-2-pupukeanone via a rhodium carbenoid C---H insertion reaction

Srikrishna, A. ; Ravi Kumar, P. ; Gharpure, Santosh J. (2001) An enantiospecific synthesis of (−)-2-pupukeanone via a rhodium carbenoid C---H insertion reaction Tetrahedron Letters, 42 (23). pp. 3929-3931. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)00585-8

Abstract

An enantiospecific synthesis of (−)-2-pupukeanone, starting from (R)-carvone employing a Michael-Michael reaction and an intramolecular rhodium carbenoid C---H insertion reaction as the key steps for the generation of the isotwistane framework, is described.

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ID Code:48739
Deposited On:15 Jul 2011 11:38
Last Modified:15 Jul 2011 11:38

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