Srikrishna, A. ; Ravi, G. (2008) A stereoselective total synthesis of (−)-seychellene Tetrahedron, 64 (11). pp. 2565-2571. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2008.01.035
Abstract
A stereoselective total synthesis of the tricyclic sesquiterpene (−)-seychellene, starting from (R)-carvone via (R)-3-methylcarvone has been accomplished, employing a combination of intermolecular Michael addition-intramolecular Michael addition sequence, a stereoselective hydrogenation, and an intramolecular alkylation reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Seychellene; Sesquiterpene Synthesis; Intramolecular Alkylation; Carvone; Double Michael Reaction |
| ID Code: | 48738 |
| Deposited On: | 15 Jul 2011 11:49 |
| Last Modified: | 15 Jul 2011 11:49 |
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