Srikrishna, A. ; Hemamalini, P. ; Veera Raghava Sharma, G. (1991) A regio and stereospecific radical annulation route to chiral tricyclo[4.3.1.o3,7]decane (isotwistane) system1 synthesis of (+)-10-α-naphthyl-5-epi-pupukean-9-one Tetrahedron Letters, 32 (45). pp. 6609-6610. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4039(91)80234-W
Abstract
Contrary to that of phenyl derivative 1 the radical 4 adds to radicophiles in an inter- followed by intra-molecular radical Michael addition (radical annulation), furnishing a novel route to chiral isotwistanes 5.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Radical Cyclisation; Annulation; Isotwistane; Pupukeanone |
| ID Code: | 48733 |
| Deposited On: | 15 Jul 2011 11:27 |
| Last Modified: | 15 Jul 2011 11:27 |
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