Srikrishna, Adusumilli ; Krishnan, Kathiresan ; Yelamaggad, Channabasaveshwar V. (1992) Regiocontrol in the cyclopropane ring cleavage of tricyclo[4.4.0.01,3]decanes to hydrindane and decalin systems Tetrahedron, 48 (44). pp. 9725-9734. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)81189-3
Abstract
Lithium-liquid ammonia reduction of the cyclopropyl β-ketoester 2̲ furnished a 1:1 mixture of hydrindane and decalin systems 3̲ and 4̲. Whereas under the same conditions the ketones 5̲ and 6̲ furnished the hydrindanones 10̲ and 13̲; and the hydroxy ester 7̲ furnished the decalin system 14̲, via the regiospecific cleavage of either C3—C2 bond or C3—C1 bond.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cyclopropanes; Li-liquid Ammonia Reduction; Hydrindane; Decalin |
| ID Code: | 48709 |
| Deposited On: | 15 Jul 2011 11:27 |
| Last Modified: | 15 Jul 2011 11:27 |
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