Srikrishna, Adusumilli ; Pardeshi, Vijendra H. ; Satyanarayana, Gedu (2008) Enantiospecific approaches to bicyclic vibsanes: a ring-closing metathesis reaction-based strategy to functionalized bicyclo[4.3.1]decanes Tetrahedron: Asymmetry, 19 (16). pp. 1984-1991. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2008.08.012
Abstract
An enantiospecific synthesis of functionalized bicyclo[4.3.1]decane, the bicyclic core system present in some bi- and tricyclic vibsane diterpenoids, for example, vibsanin E, via an RCM reaction of 2,6-diallylcarvone derivatives is described. It has been further extended to the synthesis of tricyclo[6.4.1.01,5]tridecanes starting from 2,6,6-triallylcarvones.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 48707 |
| Deposited On: | 15 Jul 2011 11:52 |
| Last Modified: | 15 Jul 2011 11:52 |
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