Srikrishna, Adusumilli ; Nagamani, Shankarnarayan A. ; Jagadeesh, Setti G. (2005) The first enantioselective synthesis of (−)-microbiotol and (+)-β-microbiotene Tetrahedron: Asymmetry, 16 (9). pp. 1569-1571. ISSN 0957-4166
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2005.03.009
Abstract
The first enantioselective total synthesis of (−)-microbiotol and (+)-β-microbiotene, sesquiterpenes containing three neighboring quaternary carbon atoms belonging to the cyclocuparane group, starting from cyclogeraniol employing a Sharpless-Katsuki asymmetric epoxidation, a boron trifluoride etherate mediated epoxide rearrangement and an intramolecular diazo ketone cyclopropanation as key steps, is described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 48702 |
| Deposited On: | 15 Jul 2011 11:45 |
| Last Modified: | 15 Jul 2011 11:45 |
Repository Staff Only: item control page
