Enantioselective total synthesis of valeriananoids AC

Srikrishna, A. ; Satyanarayana, G. (2004) Enantioselective total synthesis of valeriananoids AC Organic Letters, 6 (14). pp. 2337-2339. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol049341y

Related URL: http://dx.doi.org/10.1021/ol049341y

Abstract

The first enantioselective total synthesis of valeriananoids A-C (−)-1-3 is reported starting from the readily available monoterpene (R)-carvone, employing a tandem intermolecular Michael addition-intramolecular Michael addition-alkylation sequence and an electron-transfer-mediated 6-endo-trig cyclization as key steps.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:48685
Deposited On:15 Jul 2011 11:45
Last Modified:15 Jul 2011 11:45

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