Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (−)-Cucumin H

Srikrishna, A. ; Dethe, Dattatraya H. (2003) Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (−)-Cucumin H Organic Letters, 5 (13). pp. 2295-2298. ISSN 1523-7060

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/ol034635p

Related URL: http://dx.doi.org/10.1021/ol034635p

Abstract

The first total synthesis of the sesquiterpene (−)-cucumin H, a linear triquinane isolated from Macrocystidia cucumis, has been accomplished starting from (R)-limonene employing two different cyclopentannulation methodologies, which in addition to confirming the structure also established the absolute configuration of the natural product.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:48680
Deposited On:15 Jul 2011 11:45
Last Modified:15 Jul 2011 11:45

Repository Staff Only: item control page