Srikrishna, A. ; Dethe, Dattatraya H. (2003) Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (−)-Cucumin H Organic Letters, 5 (13). pp. 2295-2298. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol034635p
Related URL: http://dx.doi.org/10.1021/ol034635p
Abstract
The first total synthesis of the sesquiterpene (−)-cucumin H, a linear triquinane isolated from Macrocystidia cucumis, has been accomplished starting from (R)-limonene employing two different cyclopentannulation methodologies, which in addition to confirming the structure also established the absolute configuration of the natural product.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 48680 |
Deposited On: | 15 Jul 2011 11:45 |
Last Modified: | 15 Jul 2011 11:45 |
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