Facile one-pot synthesis of macrobicyclic/macrotricyclic cryptands: effect of reactant concentrations

Das, Gopal ; Tripathi, Punam ; Tripathi, Alka ; Bharadwaj, Parimal K. (2000) Facile one-pot synthesis of macrobicyclic/macrotricyclic cryptands: effect of reactant concentrations Tetrahedron Letters, 56 (11). pp. 1501-1504. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(00)00035-1

Abstract

Under high concentration conditions, tripodal trialdehyde 1 undergoes [2+3] Schiff base condensation with linear aliphatic diamines at room temperature to form macrobicyclic cryptands while two tripodal trialdehydes 1 or 2 undergo [2+2] Schiff base condensation with two tripodal triamines to form macrotricylic cryptands. Another macrotricyclic cryptand is formed via [4+6] amidation reaction.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Macrobicyclic/Macrotricyclic Cryptands; Schiff Base; One-pot Synthesis
ID Code:4862
Deposited On:18 Oct 2010 06:27
Last Modified:18 May 2011 09:00

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