Pokharkar, Varsha ; Sivaram, S. (1995) Poly(alkylene carbonate)s by the carbonate interchange reaction of aliphatic diols with dimethyl carbonate: synthesis and characterization Polymer, 36 (25). pp. 4851-4854. ISSN 0032-3861
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0032-3861(95)99302-B
Abstract
Poly(alkylene carbonate)s have been synthesized by the melt-phase interchange reaction of aliphatic diols with dimethyl carbonate. Aliphatic polycarbonates with inherent viscosities of 0.3 to 0.8 dlg−1 have been obtained. Polycarbonates derived from alicyclic diols show a Tg below room temperature and a Tm in the range 50-60°C. However, the polycarbonate derived from a cyclic diol, namely 1,4-bis(hydroxymethyl)-cyclohexane, shows a Tg of + 35°C and a Tm of + 97°C, the highest yet reported for this class of polymers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Poly(alkylene carbonate)s; Carbonate Interchange Reaction; Dimethyl Carbonate |
| ID Code: | 48573 |
| Deposited On: | 14 Jul 2011 14:16 |
| Last Modified: | 14 Jul 2011 14:16 |
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