Sivaram, S. ; Upadhyay, V. K. ; Bhardwaj, I. S. (1981) Synthesis, characterization and polycondensation of bis-(4-hydroxybutyl) terephthalate Polymer Bulletin, 5 (3-4). pp. 159-166. ISSN 0170-0839
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Official URL: http://www.springerlink.com/content/t742138035106x...
Related URL: http://dx.doi.org/10.1007/BF00265160
Abstract
Monomeric Bis-(4-hydroxybutyl) terephthalate has been synthesized and characterized. Titanium iso-propoxide has been found to be a superior catalyst for transesterification compared to metal acetates. Further polycondensation of Bis (HBT) yields poly (1,4-butylene terephthalate). The effect of various titanium derived catalysts on the polycondensation of Bis (HBT) has been studied. The catalytic efficiency of these derivatives is ascribed to their relative hydrolytic stability and the degree of interaction between the carbonyl oxygen and the metal.
Item Type: | Article |
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Source: | Copyright of this article belongs to Springer. |
ID Code: | 48491 |
Deposited On: | 14 Jul 2011 10:14 |
Last Modified: | 14 Jul 2011 10:14 |
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