Ghosh, Sujit K. ; Bharadwaj, Parimal K. (2005) Metal-organic framework H-bonded like a polycatenane: coexistence of acyclic water trimer and nonamer Inorganic Chemistry, 44 (16). pp. 5553-5555. ISSN 0020-1669
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/ic050727u
Related URL: http://dx.doi.org/10.1021/ic050727u
Abstract
Pyridine-2,6-dicarboxylic acid and 1,2-di-4-pyridylethylene react hydrothermally with nickel(II) nitrate, forming a metal-organic framework that forms a polycatenane-like structure through H-bonding interactions between water molecules and carboxylate O atoms with void spaces. Discrete acyclic trimeric and nonameric water clusters occupy the voids in the structures. X-ray powder diffraction and X-ray structure analysis have been used to characterize this compound. Crystal data for 1 {(3dpeH2)[Ni(pdc)2]3·15H2O}: monoclinic space group P21/c, a = 24.730(5) Å, b = 19.895(2) Å, c = 17.257(4) Å, β = 104.832(5)°, V = 8208(4) Å3, Z = 4, R1 = 0.0429, wR2 = 0.1072, and S = 1.051.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 4831 |
| Deposited On: | 18 Oct 2010 06:34 |
| Last Modified: | 18 May 2011 08:14 |
Repository Staff Only: item control page
