Investigations of pressure induced structural phase transformations in pentaerythritol

Garg, Nandini ; Sharma, Surinder M. ; Sikka, S. K. (2005) Investigations of pressure induced structural phase transformations in pentaerythritol Solid State Communications, 136 (1). pp. 56-61. ISSN 0038-1098

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.ssc.2005.05.017

Abstract

We have investigated the pressure induced structural changes in pentaerythritol {2,2-bis-(hydroxymethyl)-1,3-propanediol} with the help of X-ray diffraction studies. Our results show that this compound undergoes transformations to a lower symmetry phase between 5.2-5.9 GPa. It further undergoes phase transformations at ~8.5 and ~11 GPa; eventually evolving to a disordered phase beyond 14-15 GPa in agreement with our earlier Raman studies. On release of pressure from 18.5 GPa, the compound transforms back to the initial tetragonal phase.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:A. Molecular Solids; D. Phase Transitions; E. X-ray Diffraction
ID Code:48210
Deposited On:13 Jul 2011 14:27
Last Modified:12 Jul 2012 07:01

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