Mishra, Ajay K. ; Murli, Chitra ; Sharma, Surinder M. (2008) High pressure Raman spectroscopic study of deuterated γ-glycine The Journal of Physical Chemistry B, 112 (49). pp. 15867-15874. ISSN 1089-5647
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp806381e
Related URL: http://dx.doi.org/10.1021/jp806381e
Abstract
Raman spectroscopic investigations of deuterated γ-glycine, carried out up to 21 GPa, indicate emergence of a new phase, which is similar to the δ-phase, reported to be formed from the undeuterated γ-glycine at 3 GPa and the transformation to this phase is complete by 6 GPa. Observed pressure -induced variations in CD2 and N-D stretching modes indicate significant changes in the hydrogen-bonding interactions. Around ~15 GPa, splitting of CD2 and C-C stretching modes and discontinuous changes in the slope of CO2 and N-D stretching modes indicate another structural rearrangement across this pressure. The Raman spectra of retrieved phase at ambient conditions suggest that it may be a layered structure similar to the ζ-phase reported to be formed on decompression of the nondeuterated δ-glycine.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 48170 |
Deposited On: | 14 Jul 2011 08:30 |
Last Modified: | 14 Jul 2011 08:30 |
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