Quantum-coupled single-electron thermal to electric conversion scheme

Abstract

Thermal to electric energy conversion with thermophotovoltaics relies on radiation emitted by a hot body, which limits the power per unit area to that of a blackbody. Microgap thermophotovoltaics take advantage of evanescent waves to obtain higher throughput, with the power per unit area limited by the internal blackbody, which is n² higher. We propose that even higher power per unit area can be achieved by taking advantage of thermal fluctuations in the near-surface electric fields. For this, we require a converter that couples to dipoles on the hot side, transferring excitation to promote carriers on the cold side which can be used to drive an electrical load. We analyze the simplest implementation of the scheme, in which excitation transfer occurs between matched quantum dots. Next, we examine thermal to electric conversion with a lossy dielectric (aluminum oxide) hot-side surface layer. We show that the throughput power per unit active area can exceed the n² blackbody limit with this kind of converter. With the use of small quantum dots, the scheme becomes very efficient theoretically, but will require advances in technology to fabricate.