Waghmode, Suresh B. ; Sabne, Smita M. ; Sivasanker, S. (2001) Liquid phase oxidation of amines to azoxy compounds over ETS-10 molecular sieves Green Chemistry, 3 (6). pp. 285-288. ISSN 1463-9262
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/2001...
Related URL: http://dx.doi.org/10.1039/B105316G
Abstract
A convenient method for the oxidation of aryl amines to azoxybenzenes with H2O2 or tertiary butyl hydroperoxide over the titanosilicate ETS-10 is reported. Over ETS-10, aniline is transformed into azoxybenzene in greater than 97% yield with H2O2 as the oxidant. Substituted anilines are also transformed in good yields. Yield and H2O2 efficiency depend largely on experimental parameters such as catalyst concentration, H2O2: substrate mole ratio and the nature of the solvent.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 47748 |
| Deposited On: | 12 Jul 2011 14:38 |
| Last Modified: | 12 Jul 2011 14:38 |
Repository Staff Only: item control page
