Sudhakar Reddy, J. ; Sivasanker, S. ; Ratnasamy, P. (1991) Selective oxidation of n-hexane over a titanium silicate molecular sieve with MEL structure Journal of Molecular Catalysis, 70 (3). pp. 335-342. ISSN 0304-5102
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0304-5102(91)80128-P
Abstract
The selective oxidation of n-hexane to secondary alcohols and ketones has been carried out with hydrogen peroxide using TS-2, a titanium silicate molecular sieve, as the catalyst. TS-2 is found to be highly selective in the oxidation of alkanes. The influence of various parameters, such as the Ti/(Si+Ti) ratio of TS-2, its concentration, the temperature of the reaction, the feed ratio (n-C6:H2O2), the nature of the solvent and the substrate (reactant) size and shape, on the activity and selectivity in the oxyfunctionalization reaction are reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 47723 |
| Deposited On: | 12 Jul 2011 06:35 |
| Last Modified: | 05 Jul 2012 08:18 |
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