Sharma, Sagar ; Baligar, Rajesh S. ; Singh, Harkesh B. ; Butcher, Ray J. (2009) Reaction of a metallamacrocycle leading to a mercury(II)···palladium(II)···mercury(II) interaction Angewandte Chemie International Edition, 48 (11). pp. 1987-1990. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200805121
Abstract
All wrapped up: The reaction of a 22-membered macrocycle derived from bis(o-formylphenyl)mercury and 1,2-phenylenediamine with palladium(II) results in cleavage of the macrocycle and concomitant formation of a trimetallic complex (see picture; phenyl rings truncated for clarity). The nature of the HgII···PdII···HgII interaction was investigated by theoretical studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Helical Structures; Mercury; Metallacycles; Metal-metal Interactions; Palladium |
| ID Code: | 47624 |
| Deposited On: | 11 Jul 2011 13:45 |
| Last Modified: | 11 Jul 2011 13:45 |
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