Structure of trimethyltelluronium bis(4,5-dimercapto-1,3-dithiole-2-thionato)aurate(III)

Swaminathan, K. ; Carroll, Patrick J. ; Kochurani, ; Singh, Harkesh B. ; Bhargava, H. D. (1993) Structure of trimethyltelluronium bis(4,5-dimercapto-1,3-dithiole-2-thionato)aurate(III) Acta Crystallographica Section C, 49 . pp. 1243-1246. ISSN 0108-2701

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Official URL: http://scripts.iucr.org/cgi-bin/paper?cr1020

Related URL: http://dx.doi.org/10.1107/S0108270193002999

Abstract

[Te(CH)][Au(CS)], M=762.38, triclinic, P1, a=9.878 (1), b=12.326 (1), c=16.512 (3) Å, α=102.37 (1), β=91.05 (2), γ=94.22 (1)°, V=1957.2 Å, Z=4, D(flotation)=2.591, D=2.587 g cm, λ(Mo Kα)=0.7107 Å, μ=99.86 cm, F(000)=1416, T=295 K, R=0.061, wR=0.075 for 6401 unique reflections. The two independent anions in the asymmetric unit are planar and the planes are nearly parallel to each other. The anions and cations are involved in short intermolecular Au···S, S···S and Te···S contacts.

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Deposited On:11 Jul 2011 13:36
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