Manjare, Sudesh T. ; Butcher, Ray J. ; Singh, Harkesh B. (2009) N-[2-(2-Bromobenzylamino)phenyl]-N-butylformamide Acta Crystallographica Section E, 65 . o2826_1-o2826_12. ISSN 1600-5368
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Official URL: http://scripts.iucr.org/cgi-bin/paper?ds2009
Related URL: http://dx.doi.org/10.1107/S1600536809042883
Abstract
The title compound, C18H21BrN2O, crystallizes with two molecules (A and B) in the asymmetric unit (Z'=2). The major differences between the two molecules are related to the conformations adopted by their n-butyl side chains. The phenyl rings in both molecules are almost perpendicular, making dihedral angles of 79.2 (3) and 80.8 (3)°. The amide units are planar (r.m.s. deviations of 0.0018 and 0.021 Å ) and almost perpendicular to the phenyl rings to which they are attached [dihedral angles of 68.9 (4) and 71.1 (4)°]. In the crystal, molecules A and B each form only an intermolecular N-H···O hydrogen bond with an adjacent molecule of the same kind. There are no significant intermolecular interactions between molecules A and B.
Item Type: | Article |
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Source: | Copyright of this article belongs to International Union of Crystallography. |
ID Code: | 47607 |
Deposited On: | 11 Jul 2011 13:45 |
Last Modified: | 11 Jul 2011 13:45 |
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