Isolation and reactivity of an unusually stable organoselenenyl azide

Srivastava, Kriti ; Chakraborty, Tapash ; Singh, Harkesh B. ; Singh, Udai P. ; Butcher, Ray J. (2010) Isolation and reactivity of an unusually stable organoselenenyl azide Dalton Transactions, 39 (42). pp. 10137-10141. ISSN 1477-9226

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2010...

Related URL: http://dx.doi.org/10.1039/C0DT00509F

Abstract

The stabilities of a series of isolated covalent selenium(II) azides such as [2-[1-(3,5-dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]selenium azide (2a), [2-(4,4-dimethyl-2-oxazolinyl)phenyl]selenenyl azide (3a), [o-(2,6-diisopropylphenyl-iminomethinyl)phenyl]selenenyl azide (4a), [o-(R)-(methylbenzyliminomethinyl)phenyl]selenenyl azide (5a) and o-formylphenylselenenyl azide (6a) are rationalized; also the reactivity of first room temperature stable azide (2a) toward 1,3-cycloaddition has been explored.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:47572
Deposited On:11 Jul 2011 13:46
Last Modified:11 Jul 2011 13:46

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