Apte, Sandeep D. ; Zade, Sanjio S. ; Singh, Harkesh B. ; Butcher, Ray J. (2003) Contrasting behavior of bis[2-(4,4-dimethyl-2-oxazolinyl)phenyl] chalcogenides (Se/Te) toward mercuric chloride: facile Ccleavage of the Te-C bond Organometallics, 22 (26). pp. 5473-5477. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om034222s
Related URL: http://dx.doi.org/10.1021/om034222s
Abstract
The reactions of R2Se (3) and R2Te (4) (R=2-(4,4-dimethyl-2-oxazolinyl)phenyl) with HgCl2 and Pd(COD)Cl2 are described. The reaction of selenoether 3 with HgCl2 affords the expected complex R2SeHgCl2 (5), which is stable in solution. In contrast, the analogous tellurium complex R2TeHgCl2 (6) undergoes slow dismutation in chlorinated solvents to give the fragments RTeCl (7) and RHgCl (8).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 47540 |
| Deposited On: | 11 Jul 2011 13:41 |
| Last Modified: | 11 Jul 2011 13:41 |
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